Rate acceleration of phosphoric acid-catalyzed Diels-Alder reaction by internal hydrogen-bonding of adjacent hydroxy group

The Brønsted acid-catalyzed Diels-Alder reaction was examined. Phosphoric acids were effective Brønsted acids for the Diels-Alder reaction of cyclohexadienones and activated by the internal hydrogen-bonding of the adjacent hydroxy group. ▪ The Brønsted acid-catalyzed Diels-Alder reaction was examine...

Full description

Saved in:
Bibliographic Details
Published inJournal of molecular catalysis. A, Chemical Vol. 278; no. 1; pp. 120 - 126
Main Authors Takagi, Ryukichi, Kondo, Asako, Ohkata, Katsuo
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier B.V 01.12.2007
Elsevier
Subjects
Brønsted acid catalyst
Catalysis
Chemistry
Diels-Alder reaction
Exact sciences and technology
General and physical chemistry
Rate acceleration
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Brønsted acid catalyst
Rate acceleration
Diels-Alder reaction
Phosphoric acid
Catalytic reaction
Brönsted acid
Hydrogen
Diels Alder addition
Catalyst
Online AccessGet full text

Cover

More Information
Summary:The Brønsted acid-catalyzed Diels-Alder reaction was examined. Phosphoric acids were effective Brønsted acids for the Diels-Alder reaction of cyclohexadienones and activated by the internal hydrogen-bonding of the adjacent hydroxy group. ▪ The Brønsted acid-catalyzed Diels-Alder reaction was examined. Phosphoric acids were effective Brønsted acids for the Diels-Alder reaction of cyclohexadienones and activated by the internal hydrogen-bonding of the adjacent hydroxy group.
ISSN:1381-1169
1873-314X
DOI:10.1016/j.molcata.2007.08.020