Polymerization of 1,4-bis[2-(N-vinyl)pyrrolyl]benzene

Polymers of 1,4-bis[2-( N -vinyl)pyrrolyl]benzene with free N -vinyl groups in side chains are synthesized in the presence of AIBN (2–5 wt %, 70°C) with a yield of up to 34% and a molecular mass of up to 11.5 × 10 3 . In the presence of cationic catalysts (Me 3 SiCl, the LiBF 4 -dimethoxyethane syst...

Full description

Saved in:
Bibliographic Details
Published inPolymer science. Series B Vol. 52; no. 3-4; pp. 193 - 197
Main Authors Trofimov, B. A., Markova, M. V., Morozova, L. V., Mikhaleva, A. I., Shmidt, E. Yu, Zorina, N. V., Hyun, Sang Heon
Format Journal Article
LanguageEnglish
Published Dordrecht SP MAIK Nauka/Interperiodica 01.04.2010
Subjects
Backbone
Catalysis
Catalysts
Cationic
Chains (polymeric)
Chemistry
Chemistry and Materials Science
Macromolecules
Polymer Sciences
Polymerization
Polymer Science Series
Role Ring
Pyrrole Ring
AIBN
Pyrrole
Online AccessGet full text

Cover

More Information
Summary:Polymers of 1,4-bis[2-( N -vinyl)pyrrolyl]benzene with free N -vinyl groups in side chains are synthesized in the presence of AIBN (2–5 wt %, 70°C) with a yield of up to 34% and a molecular mass of up to 11.5 × 10 3 . In the presence of cationic catalysts (Me 3 SiCl, the LiBF 4 -dimethoxyethane system, and BF 3 · OEt 2 ), 1,4-bis[2-( N -vinyl)pyrrolyl]benzene gives macromolecules with alternating 1,2-pyrrolene and ethylidene units in the backbone with yields of 80, 44, and 33%, respectively. The polymers demonstrate paramagnetic and luminescent properties.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
content type line 23
ISSN:1560-0904
1555-6123
DOI:10.1134/S1560090410030097