Visible-light-induced photocatalytic azotrifluoromethylation of alkenes with aryldiazonium salts and sodium triflinate

The efficient visible light photocatalytic azotrifluoromethylation of alkenes with aryldiazonium salts and sodium triflinate is described, which gave the corresponding trifluoromethylated azo compounds in generally good yields. The trifluoromethylated azo products can be easily transformed into usef...

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Published inChemical communications (Cambridge, England) Vol. 52; no. 53; pp. 8275 - 8278
Main Authors Yu, Xing-Long, Chen, Jia-Rong, Chen, Dong-Zhen, Xiao, Wen-Jing
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2016
Subjects
Alkenes
Azo
Azo compounds
Chemistry
Chemistry, Multidisciplinary
Photocatalysis
Physical Sciences
Science & Technology
Sodium
FUNCTIONALIZATION
CYCLOADDITION
PHOTOREDOX-CATALYZED TRIFLUOROMETHYLATION
DIAZONIUM SALTS
HYDROTRIFLUOROMETHYLATION
VICINAL DIFUNCTIONALIZATION
AMINOTRIFLUOROMETHYLATION
FLUORINE
ARYL
RADICALS
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Summary:The efficient visible light photocatalytic azotrifluoromethylation of alkenes with aryldiazonium salts and sodium triflinate is described, which gave the corresponding trifluoromethylated azo compounds in generally good yields. The trifluoromethylated azo products can be easily transformed into useful heterocycles and nitrogen-containing building blocks.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc03335k