A Heterogeneous Viscosity Flow Model for Liquid Transport through Nanopores Considering Pore Size and Wettability

• Published in: Molecules (Basel, Switzerland) Vol. 29; no. 13; p. 3176
• Main Authors: Chang, Yilin, Zhang, Yapu, Niu, Zhongkun, Chen, Xinliang, Du, Meng, Yang, Zhengming
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 03.07.2024
• Subjects: Behavior; boundary region; Carbon; confined effect; flow suppression; Mathematical models; Pore size; Velocity; Viscosity; Water; wettability; flow suppression; confined effect; wettability; viscosity; boundary region
• ISSN: 1420-3049; 1420-3049
• DOI: 10.3390/molecules29133176

The confinement effect in micro- and nanopores gives rise to distinct flow characteristics in fluids. Clarifying the fluid migration pattern in confined space is crucial for understanding and explaining the abnormal flow phenomena in unconventional reservoirs. In this study, flow characteristics of water and oil in alumina nanochannels were investigated with diameters ranging from 21 nm to 120 nm, and a heterogeneous viscosity flow model considering boundary fluid was proposed. Compared with the prediction of the HP equation, both types of fluids exhibit significant flow suppression in nanochannels. As the channel size decreases, the deviation degree increases. The fluid viscosity of the boundary region displays an upward trend as the channel size decreases and the influence of the interaction between the liquid and solid walls intensifies. The thickness of the boundary region gradually decreases with increasing pressure and eventually reaches a stable value, which is primarily determined by the strength of the interaction between the liquid and solid surfaces. Both the pore size and wettability are essential factors that affect the fluid flow. When the space scale is extremely small, the impact of wettability becomes more pronounced. Finally, the application of the heterogeneous flow model for permeability evaluation has yielded favorable fitting results. The model is of great significance for studying the fluid flow behavior in unconventional reservoirs.