A zeolite CAN-type aluminoborate with gigantic 24-ring channels

A cancrinite type aluminoborate with gigantic 24-ring channels has been made under solvothermal conditions using Al(i-PrO)3 as the Al source and amines as the structure directing agents. Its framework is alternately constructed from B5O10 clusters and AlO4 units, no Al-O-Al linkages exist in the str...

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Published inChemical communications (Cambridge, England) Vol. 52; no. 8; pp. 1729 - 1732
Main Authors Cao, Gao-Juan, Wei, Qi, Cheng, Jian-Wen, Cheng, Lin, Yang, Guo-Yu
Format Journal Article
LanguageEnglish
Published England 01.01.2016
Subjects
Amines
Channels
Clusters
Construction
Linkages
Three dimensional
Walls
Zeolites
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Summary:A cancrinite type aluminoborate with gigantic 24-ring channels has been made under solvothermal conditions using Al(i-PrO)3 as the Al source and amines as the structure directing agents. Its framework is alternately constructed from B5O10 clusters and AlO4 units, no Al-O-Al linkages exist in the structure. Notably, the wall of the 24-ring channels has odd 11-ring windows, resulting in an unprecedented 3D intersecting channel system.
Bibliography:ObjectType-Article-1
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content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc08164e