An insight into the mechanism of the aerobic oxidation of aldehydes catalyzed by N-heterocyclic carbenes

N-Heterocyclic carbene catalysis for the aerobic oxidation and esterification of aromatic aldehydes was monitored by ESI-MS (MS/MS) and the key intermediates were intercepted and characterized using the charge-tag strategy.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 50; no. 16; pp. 2008 - 2011
Main Authors Bortolini, O, Chiappe, C, Fogagnolo, M, Giovannini, P P, Massi, A, Pomelli, C S, Ragno, D
Format Journal Article
LanguageEnglish
Published England 01.01.2014
Subjects
Aldehydes
Aldehydes - chemistry
Carbenes
Carboxylic Acids - chemical synthesis
Carboxylic Acids - chemistry
Catalysis
Esterification
Heterocyclic Compounds - chemistry
Methane - analogs & derivatives
Methane - chemistry
Molecular Structure
Monitoring
Oxidation
Oxidation-Reduction
Strategy
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Summary:N-Heterocyclic carbene catalysis for the aerobic oxidation and esterification of aromatic aldehydes was monitored by ESI-MS (MS/MS) and the key intermediates were intercepted and characterized using the charge-tag strategy.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc48929a