Triphenylene-based tris-N-heterocyclic stannylenes

Two planar tridentate N-heterocyclic stannylenes are synthesized from the corresponding 2,3,6,7,10,11-hexaamino-triphenylene and Sn[N(TMS)2]2. Multinuclear NMR and absorption spectra of these tris-stannylenes are reported. Molecular structure of the N-benzhydryl-substituted tris-stannylene is also r...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 44; no. 34; pp. 15095 - 15098
Main Authors Hsu, Chen-Yuan, Chan, Li-Wei, Lee, Gene-Hsiang, Peng, Shie-Ming, Chiu, Ching-Wen
Format Journal Article
LanguageEnglish
Published England 14.09.2015
Subjects
Absorption spectra
Molecular structure
Nuclear magnetic resonance
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Summary:Two planar tridentate N-heterocyclic stannylenes are synthesized from the corresponding 2,3,6,7,10,11-hexaamino-triphenylene and Sn[N(TMS)2]2. Multinuclear NMR and absorption spectra of these tris-stannylenes are reported. Molecular structure of the N-benzhydryl-substituted tris-stannylene is also realized.
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ISSN:1477-9226
1477-9234
DOI:10.1039/c5dt00694e