Sequential electrophilic P-C bond formation in metal-coordinated chlorophosphines

In the presence of chloride abstractors, metal-coordinated chlorophosphines undergo facile room-temperature electrophilic substitution reactions with unsaturated organic substrates, leading to P-C bond formation. This methodology can be applied sequentially two or three times, stepwise or in one-pot...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 44; no. 19; pp. 8788 - 8791
Main Authors Jayaraman, Arumugam, Jacob, Tyler V, Bisskey, Jeff, Sterenberg, Brian T
Format Journal Article
LanguageEnglish
Published England 21.05.2015
Subjects
Bonding
Chlorides
Methodology
Phosphines
Substitution reactions
Unsaturated
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Summary:In the presence of chloride abstractors, metal-coordinated chlorophosphines undergo facile room-temperature electrophilic substitution reactions with unsaturated organic substrates, leading to P-C bond formation. This methodology can be applied sequentially two or three times, stepwise or in one-pot reactions, to form phosphines with three different substituents. The reactions are rapid and high-yielding, and can be applied to a wide range of organic substrates, making them valuable tools for P-C bond formation.
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ISSN:1477-9226
1477-9234
DOI:10.1039/c5dt01281c