Cyanation of alpha,beta-unsaturated enones by malononitrile in open air under metal-catalyst-free conditions

Cyanation of alpha,beta-unsaturated enones by employing malononitrile as the organic cyanation source has been disclosed, which proceeds efficiently at room temperature in open air under metal-catalyst-free conditions.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 48; no. 79; pp. 9879 - 9881
Main Authors Lin, Shaoxia, Wei, Ying, Liang, Fushun
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 11.10.2012
Subjects
Chemistry
Chemistry, Multidisciplinary
Malononitrile
Physical Sciences
Science & Technology
ENANTIOSELECTIVE CONJUGATE CYANATION
ARYL BROMIDES
N,N-DIMETHYLFORMAMIDE
NITRILES
HYDROCYANATION
CONSTRUCTION
CYANOSILYLATION
ASYMMETRIC CYANATION
CLEAVAGE
CARBON-CYANO
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Summary:Cyanation of alpha,beta-unsaturated enones by employing malononitrile as the organic cyanation source has been disclosed, which proceeds efficiently at room temperature in open air under metal-catalyst-free conditions.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc35528k