Preorganized assembly of three iron(II) or manganese(II) β-diketiminate complexes using a cyclophane ligand

A trinucleating cyclophane bearing three beta-diketimine arms, and the corresponding iron(II) and manganese(II) complexes have been synthesized and characterized. The three metal ions are oriented towards the internal void space, and are coordinated by a N2Br2 donor set, in which a unique combinatio...

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Published inChemical communications (Cambridge, England) Vol. 49; no. 59; pp. 6635 - 6637
Main Authors Guillet, Gary L., Sloane, Forrest T., Ermert, David M., Calkins, Matthew W., Peprah, Marcus K., Knowles, Elisabeth S., Cizmar, Erik, Abboud, Khalil A., Meisel, Mark W., Murray, Leslie J.
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 28.07.2013
Subjects
Assembly
Bearing
Benzene Derivatives - chemistry
Chemistry
Chemistry, Multidisciplinary
Ferrous Compounds - chemistry
Halides
Imines - chemistry
Ligands
Manganese - chemistry
Metal ions
Models, Molecular
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Physical Sciences
Science & Technology
Temperature
Terminals
Voids
HIGH-SPIN
COPPER(I) COMPLEXES
TRIIRON COMPLEXES
CLUSTERS
ANALOGS
ZINC-COMPLEXES
REACTIVITY
CHEMISTRY
COPOLYMERIZATION
CHLORIDE
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Summary:A trinucleating cyclophane bearing three beta-diketimine arms, and the corresponding iron(II) and manganese(II) complexes have been synthesized and characterized. The three metal ions are oriented towards the internal void space, and are coordinated by a N2Br2 donor set, in which a unique combination of mu(3), mu, and terminal coordination modes are observed for the halide donors.
Bibliography:National Science Foundation
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ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc43395a