The palladium-catalyzed cross-coupling reactions of trifluoroethyl iodide with aryl and heteroaryl boronic acid esters

The cross-coupling reactions of 1,1,1-trifluoro-2-iodoethane with aryl and heteroaryl boronic acid esters have been successfully achieved. The new protocol allows for a convenient introduction of trifluoroethyl groups into a variety of aryl and heteroaryl moieties under mild conditions.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 48; no. 66; pp. 8273 - 8275
Main Authors Liang, Apeng, Li, Xinjian, Liu, Dongfeng, Li, Jingya, Zou, Dapeng, Wu, Yangjie, Wu, Yusheng
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 25.08.2012
Subjects
Aromatic compounds
Boronic Acids - chemistry
Catalysis
Chemistry
Chemistry, Multidisciplinary
Esters
Esters - chemistry
Hydrocarbons, Fluorinated - chemistry
Iodides
Iodides - chemistry
Molecular Structure
Palladium - chemistry
Physical Sciences
Science & Technology
CHEMISTRY
METHYL
CYCLOPALLADATED-FERROCENYLIMINE
ALKYL-HALIDES
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Summary:The cross-coupling reactions of 1,1,1-trifluoro-2-iodoethane with aryl and heteroaryl boronic acid esters have been successfully achieved. The new protocol allows for a convenient introduction of trifluoroethyl groups into a variety of aryl and heteroaryl moieties under mild conditions.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc31651j