Macrocyclic Silver Coordination Compounds with bis[4-(Pyridine-2-yl)Pyrimidin-2-Ylthio]methane: Crystal Structures and Luminescent Properties

Reaction of AgX2 (X = NO3-, BF4-) with bis[4-(pyridine-2-yl)pyrimidin-2-ylthio]methane (2-bppt) gave two macrocyclic dinuclear silver coordination compounds [Ag2{?-(2-bppt)}2]X2 (X= NO3- or BF4-). Non-classical hydrogen bonding interactions as well as weak aromatic stacking forces are involved in th...

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Published inJournal of chemical research Vol. 35; no. 3; pp. 144 - 146
Main Authors Zhu, Hai-Bin, Zhang, Shu-Ying, Lu, Xin, Yang, Wen-Na
Format Journal Article
LanguageEnglish
Published London Sage Publications Ltd 01.03.2011
Subjects
Coordination compounds
Crystal structure
Hydrogen bonding
Ligands
Macrocyclic compounds
Photoluminescence
Silver
Stacking
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Summary:Reaction of AgX2 (X = NO3-, BF4-) with bis[4-(pyridine-2-yl)pyrimidin-2-ylthio]methane (2-bppt) gave two macrocyclic dinuclear silver coordination compounds [Ag2{?-(2-bppt)}2]X2 (X= NO3- or BF4-). Non-classical hydrogen bonding interactions as well as weak aromatic stacking forces are involved in their packing structures. Both compounds show intense photoluminescence governed principally by the 2-bppt ligand itself.
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ISSN:1747-5198
2047-6507
DOI:10.3184/174751911X12973456175518