Enhancing optical anisotropy of crystals by optimizing bonding electron distribution in anionic groups

The response electron distribution anisotropy (REDA) approximation was proposed to analyze the relationship between optical anisotropy and distribution of bonding electrons in compounds. Further, the optical anisotropy of tetrahedral chromophore compounds with common small birefringence can be enhan...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 53; no. 19; pp. 2818 - 2821
Main Authors Lei, Bing-Hua, Yang, Zhihua, Pan, Shilie
Format Journal Article
LanguageEnglish
Published England 02.03.2017
Subjects
Anisotropy
Approximation
Birefringence
Chemical bonds
Electron distribution
Mathematical analysis
Optical properties
Optimization
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Summary:The response electron distribution anisotropy (REDA) approximation was proposed to analyze the relationship between optical anisotropy and distribution of bonding electrons in compounds. Further, the optical anisotropy of tetrahedral chromophore compounds with common small birefringence can be enhanced and excellent nonlinear optical properties can be obtained by optimizing the distribution.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc09986f