A novel metal-organic framework based on bismuth and trimesic acid: synthesis, structure and properties

A bismuth based metal-organic framework ([Bi(BTC)(DMF)]·DMF (CH3OH)2, Bi-BTC) with a novel topology structure is synthesized by a solvothermal method. Bi-BTC crystalizes in the P21/n space group, exhibits a novel 3D framework consisting of trimesic acid (H3BTC) linked with {Bi2O14} units and contain...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 44; no. 37; pp. 16238 - 16241
Main Authors Wang, Guanzhi, Liu, Yuanyuan, Huang, Baibiao, Qin, Xiaoyan, Zhang, Xiaoyang, Dai, Ying
Format Journal Article
LanguageEnglish
Published England 01.01.2015
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Summary:A bismuth based metal-organic framework ([Bi(BTC)(DMF)]·DMF (CH3OH)2, Bi-BTC) with a novel topology structure is synthesized by a solvothermal method. Bi-BTC crystalizes in the P21/n space group, exhibits a novel 3D framework consisting of trimesic acid (H3BTC) linked with {Bi2O14} units and contains two helix chains which assemble regularly. In addition, we investigated the photophysical properties of Bi-BTC which shows high activity of O2 production in photocatalysis.
ISSN:1477-9226
1477-9234
DOI:10.1039/c5dt03111g