Novel phenanthroline-diaryldiazadiene ligands with heteroditopic coordination spheres

1,10-Phenanthroline-5,6-diaryldiazadienes are key structures for the development of novel heterodinuclear photocatalysts and for the construction of extended heterocycles of potential biological use. Herein, the first examples of this compound family are presented together with a wide range of initi...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 44; no. 35; pp. 15404 - 15407
Main Authors Sorsche, Dieter, Pehlken, Christian, Baur, Christian, Rommel, Sebastian, Kastner, Katharina, Streb, Carsten, Rau, Sven
Format Journal Article
LanguageEnglish
Published England 21.09.2015
Subjects
Alkenes - chemical synthesis
Alkenes - chemistry
Aza Compounds - chemical synthesis
Aza Compounds - chemistry
Biological
Construction
Coordination Complexes - chemical synthesis
Coordination Complexes - chemistry
Derivatives
Iridium - chemistry
Ligands
Models, Molecular
Phenanthrolines - chemical synthesis
Phenanthrolines - chemistry
Photocatalysis
Photocatalysts
Strategy
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Summary:1,10-Phenanthroline-5,6-diaryldiazadienes are key structures for the development of novel heterodinuclear photocatalysts and for the construction of extended heterocycles of potential biological use. Herein, the first examples of this compound family are presented together with a wide range of initial reactivity studies. Synthetic strategies are presented to access the two first derivatives of the ligand and to accomplish subsequent metal coordination to the phenanthroline sphere.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1477-9226
1477-9234
DOI:10.1039/c5dt02383a