Cyclometallated gold(III) hydroxides as versatile synthons for Au-N, Au-C complexes and luminescent compounds

The gold(III) hydroxide kappa(3)-(C boolean AND N boolean AND C)* Au(OH) reacts with C-H and N-H compounds and arylboronic acids to produce a range of perfluoroaryls, N-heterocyclic and alkynyl compounds in high yields; some of which show unexpectedly strong modulation of their photoluminescence fro...

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Published inChemical communications (Cambridge, England) Vol. 48; no. 58; pp. 7247 - 7249
Main Authors Rosca, Dragos-Adrian, Smith, Dan A., Bochmann, Manfred
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 25.07.2012
Subjects
Chemistry
Chemistry, Multidisciplinary
Gold
Hydroxides
Modulation
Photoluminescence
Physical Sciences
Science & Technology
GOLD
PHOTOCHEMICAL PROPERTIES
SCOPE
CRYSTAL-STRUCTURE
REACTIVITY
CHEMISTRY
DERIVATIVES
H ACTIVATION
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Summary:The gold(III) hydroxide kappa(3)-(C boolean AND N boolean AND C)* Au(OH) reacts with C-H and N-H compounds and arylboronic acids to produce a range of perfluoroaryls, N-heterocyclic and alkynyl compounds in high yields; some of which show unexpectedly strong modulation of their photoluminescence from yellow to blue [(C boolean AND N boolean AND C)* = 2,6-(C6H3But)(2)pyridine].
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ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc33104g