A simple analytical model for signal amplification by reversible exchange (SABRE) process
We demonstrate an analytical model for the description of the signal amplification by reversible exchange (SABRE) process. The model relies on a combined analysis of chemical kinetics and the evolution of the nuclear spin system during the hyperpolarization process. The presented model for the first...
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Published in | Physical chemistry chemical physics : PCCP Vol. 18; no. 1; pp. 89 - 93 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
England
07.01.2016
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Subjects | |
Online Access | Get full text |
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Summary: | We demonstrate an analytical model for the description of the signal amplification by reversible exchange (SABRE) process. The model relies on a combined analysis of chemical kinetics and the evolution of the nuclear spin system during the hyperpolarization process. The presented model for the first time provides rationale for deciding which system parameters (i.e. J-couplings, relaxation rates, reaction rate constants) have to be optimized in order to achieve higher signal enhancement for a substrate of interest in SABRE experiments. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1463-9076 1463-9084 |
DOI: | 10.1039/c5cp05134g |