Synthesis of Al/Cu core–shell particles through optimization of galvanic replacement method in alkaline solution

• Published in: International journal of materials research Vol. 112; no. 6; pp. 439 - 447
• Main Authors: Ali, Rashid, Ali, Fahad, Zahoor, Aqib, Nawaz Shahid, Rub, ul HaqTariq, Naeem, Ullah, Saad, Mahmood, Arshad, Shah, Attaullah, Bin Awais, Hasan
• Format: Journal Article
• Language: English
• Published: Stuttgart De Gruyter 31.05.2021; Carl Hanser Verlag
• Subjects: Al/Cu core-shell; Aluminum; ANOVA; Complexing agents; Copper; Copper chloride; Copper sulfate; Core-shell particles; Deposition; Ethylenediaminetetraacetic acids; Galvanic replacement reaction; Optimization; Taguchi method; Taguchi methods
• ISSN: 2195-8556; 1862-5282; 2195-8556
• DOI: 10.1515/ijmr-2020-8167

In this work, Al/Cu core–shell particles were successfully synthesized through an optimized galvanic replacement method. For this purpose, a uniform and dense copper layer was deposited on aluminum particles in an alkaline solution. The effects of four deposition factors, i. e. (i) molar ratio EDTA-2Na/CuSO · 5H O, (ii) molar ratio CuCl /Al powder, (iii) and (iv) temperature were systematically studied and optimized using the Taguchi orthogonal (L9) method. It was observed that molar ratio EDTA-2Na/CuSO · 5H O and temperature are the most affecting factors in the deposition process. By increasing their levels, copper deposition increases within a specified time. The X-ray diffraction and scanning electron microscopy/ energy-dispersive X-ray spectroscopy results revealed the formation of homogeneous nanostructured Cu shells around Al particles. The results revealed that to achieve maximum copper deposition on Al powder; molar ratio EDTA-2Na. 2H O/CuSO . 5H O, molar ratio CuCl /Al powder, and temperature of the deposition bath should be 2.0, 0.05, 8.8 and 55 °C, respectively.