An active catalytic system for Suzuki Miyaura cross-coupling reactions using low levels of palladium loading

An easily available Pd(OAc)2/(2-(anthracen-9-0-1H-inden-3-0) d cyclohexylphosphine/toluene/PrOH/ water catalytic system was developed, which shows high catalytic activity in the Suzuki-Miyaura cross coupling reactions of a diverse array of aryl and heteroaryl chlorides with Pd loadings down to 0.01...

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Published inOrganic & biomolecular chemistry Vol. 15; no. 18; pp. 3924 - 3929
Main Authors Yan, Meng-Qi, Yuan, Jia, Lan, Fang, Zeng, Si-Hao, Gao, Meng-Yue, Liu, Sheng-Hua, Chen, Jian, Yu, Guang-Ao
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 10.05.2017
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
ROOM-TEMPERATURE
NANOPARTICLES
AMINATION
PHOSPHINE LIGAND
COMPLEXES
HETEROARYL BORONIC ACIDS
PPM
EFFICIENT
ARYLBORONIC ACIDS
ARYL CHLORIDES
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Summary:An easily available Pd(OAc)2/(2-(anthracen-9-0-1H-inden-3-0) d cyclohexylphosphine/toluene/PrOH/ water catalytic system was developed, which shows high catalytic activity in the Suzuki-Miyaura cross coupling reactions of a diverse array of aryl and heteroaryl chlorides with Pd loadings down to 0.01 mol%.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1477-0520
1477-0539
DOI:10.1039/C7OB00178A