Hybrid of multi‐dimensional fillers for thermally enhanced polyamide 12 composites fabricated by selective laser sintering

• Published in: Polymer composites Vol. 42; no. 8; pp. 4105 - 4114
• Main Authors: Yuan, Yue, Hu, Huanbo, Wu, Wei, Zhao, Zhengbai, Du, Xiangyun, Wang, Zhengyi
• Format: Journal Article
• Language: English
• Published: Hoboken, USA John Wiley & Sons, Inc 01.08.2021; Blackwell Publishing Ltd; Wiley Blackwell (John Wiley & Sons)
• Subjects: Aluminum oxide; Boron nitride; Carbon nanotubes; Crystallization; Dielectric properties; Fillers; Laser sintering; Mechanical properties; Morphology; polyamide 12; Polyamide resins; Polymer matrix composites; Rapid prototyping; selective laser sintering; Sintering (powder metallurgy); Synergistic effect; Thermal conductivity; Thermal management; Three dimensional printing
• ISSN: 0272-8397; 1548-0569
• DOI: 10.1002/pc.26120

Selective laser sintering (SLS) is an additive manufacturing technology that can provide a novel strategy to manufacture complex polymer‐based composites with tailored properties. In this study, polyamide 12 (PA12) composite powders based on Al2O3, boron nitride (BN), and carbon nanotubes (CNTs) were prepared via a two‐step mixing approach. Morphology characterization techniques indicated that the fillers were uniformly dispersed in the PA12 matrix as expected. Under the optimum 3D‐printing parameters, the fabrication of SLS parts with high filler loading could be obtained. With 40 wt% Al2O3, 8 wt% BN, and 2 wt% CNT hybrid fillers, the thermal conductivity of PA12 composites could reach 1.09 W/mK. It could be attributed to the synergistic effect of multi‐dimensional fillers to form dense and continuous thermal conduction paths. The factors influencing the performance of PA12 composites such as melting and crystallization behaviors, dielectric properties, and mechanical properties were also discussed. The results show that these composites have favorable dielectric and mechanical properties. Overall, the PA12 composites fabricated by SLS technology in this study exhibit excellent thermal management ability. Carbon nanotubes with high aspect ratio were introduced to partly replace boron nitride plates in the polyamide‐12 matrix, with the expectation that it would aid the formation of more continuous and denser thermal conductive networks. The sintered samples possess excellent thermal conductivity and favorable mechanical properties.