Synthesis of new alkenyl iodobenzoate derivatives via Kharasch-Sosnovsky reaction using tert-butyl iodo benzoperoxoate and copper (I) iodide
The synthesis of new alkenyl iodobenzoate derivatives as allylic esters was investigated via the reaction of tert -butyl iodobenzoperoxoate with alkenes in the presence of copper salts. The best result was obtained using tert -butyl-iodobenzoperoxoate in the presence of copper (I) iodide (5 mol%) in...
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Published in | Journal of chemical sciences (Bangalore, India) Vol. 132; no. 1 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
New Delhi
Springer India
01.12.2020
Springer Nature B.V |
Subjects | |
Online Access | Get full text |
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Summary: | The synthesis of new alkenyl iodobenzoate derivatives as allylic esters was investigated
via
the reaction of
tert
-butyl iodobenzoperoxoate with alkenes in the presence of copper salts. The best result was obtained using
tert
-butyl-iodobenzoperoxoate in the presence of copper (I) iodide (5 mol%) in refluxing acetonitrile with good yield (92%) in 32 h. The structure of peresters and alkenyl iodobenzoate derivatives were characterized on the basis of their FT-IR,
1
HNMR,
13
CNMR, and Mass spectra.
Graphic abstract
The preparation of new iodo-allylic esters from alkenes in the presence of copper salts in good to excellent yields is reported in this article. |
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ISSN: | 0974-3626 0973-7103 |
DOI: | 10.1007/s12039-020-01852-8 |