High-performance Si/VO2-nanorod heterojunction photodetector based on photothermoelectric effect for detecting human radiation

• Published in: Rare metals Vol. 43; no. 3; pp. 1177 - 1185
• Main Authors: Guo, Fu-Hai, Hao, Lan-Zhong, Yu, Wei-Zhuo, Li, Si-Qi, Liu, Guan-Chu, Hao, Jing-Yi, Liu, Yun-Jie
• Format: Journal Article
• Language: English
• Published: Beijing Nonferrous Metals Society of China 01.03.2024; Springer Nature B.V
• Subjects: Biomaterials; Broadband; Chemistry and Materials Science; Energy; Heterojunctions; Magnetron sputtering; Materials Engineering; Materials Science; Metallic Materials; Nanorods; Nanoscale Science and Technology; Optoelectronics; Original Article; Photometers; Physical Chemistry; Radiation; Respiration; Thermal radiation; Vanadium dioxide; Vanadium oxides; Human radiation and respiration sensing; Photothermoelectric; Photodetector; Vanadium dioxide; Heterojunction
• ISSN: 1001-0521; 1867-7185
• DOI: 10.1007/s12598-023-02497-5

As a typical candidate of optoelectronic materials, vanadium dioxide (VO 2 ) has wide applications in photodetectors (PDs), but is still challenging in largely enhancing the photodetecting performance for low-power human radiation. Herein, high-performance Si/VO 2 nanorods (NRs) heterojunction PDs based on the photothermoelectric (PTE) effect are presented. The uniform VO 2 -NRs array films were deposited on Si by using magnetron sputtering technique, and a Si/VO 2 heterojunctions were fabricated. The device exhibits a four-stage photoresponse and broadband photoresponse from ultraviolet to long-wavelength infrared. Benefited from the unique nanorods structure and the strong PTE effect, the fabricated device exhibits a large enhancement of the photodetecting performance, showing an ultrahigh photodetectivity of 1.6 × 10 13 Jones and ultrafast response rates with a rising-edge time of ~ 65.0 μs, three orders of magnitude higher than other VO 2 -based devices. Furthermore, the device exhibits unique abilities to detect human radiation even when the human fingers are far away from the device surface up to 10.0 cm. Additionally, the fabricated Si/VO 2 devices can also be applied as breath sensors to distinguish different breathing patterns. These results supply an effective route to design high-performance photodetectors toward detecting human thermal radiation and respiration. Graphical abstract