Recent advances in kinetic and thermodynamic regulation of magnesium hydride for hydrogen storage

• Published in: Rare metals Vol. 42; no. 9; pp. 2906 - 2927
• Main Authors: Yang, Hang, Ding, Zhao, Li, Yu-Ting, Li, Shao-Yuan, Wu, Ping-Keng, Hou, Quan-Hui, Zheng, Yang, Gao, Biao, Huo, Kai-Fu, Du, Wen-Jia, Shaw, Leon L.
• Format: Journal Article
• Language: English
• Published: Beijing Nonferrous Metals Society of China 01.09.2023; Springer Nature B.V
• Subjects: Ball milling; Biomaterials; Catalysis; Chemistry and Materials Science; Destabilization; Energy; Hydrogen storage; Hydrogen storage materials; Magnesium; Materials Engineering; Materials Science; Metallic Materials; Nanoscale Science and Technology; Optimization; Physical Chemistry; Review; Spraying; Thermodynamics; Thermodynamics; Hydrogen storage; Magnesium hydride; Kinetics
• ISSN: 1001-0521; 1867-7185
• DOI: 10.1007/s12598-023-02306-z

Developing safer and more efficient hydrogen storage technology is a pivotal step to realizing the hydrogen economy. Owing to the lightweight, high hydrogen storage density and abundant reserves, MgH 2 has been widely studied as one of the most promising solid-state hydrogen storage materials. However, defects such as stable thermodynamics, sluggish kinetics and rapid capacity decay have seriously hindered its practical application. This article reviews recent advances in catalyst doping and nanostructures for improved kinetic performance of MgH 2 /Mg systems for hydrogen release/absorption, the tuning of their thermodynamic stability properties by alloying and reactant destabilization, and the dual thermodynamic and kinetic optimization of the MgH 2 /Mg system achieved by nanoconfinement with in situ catalysis and ball milling with in situ aerosol spraying, aiming to open new perspectives for the scale-up of MgH 2 for hydrogen storage applications. Graphic Abstract