A base-stabilised arsenic(III) dication

A bulky guanidinate ligand has been utilized in supporting a dichloroarsine, which is an excellent precursor to an arsenium cation and a 2,2'-bipyridine base stabilised arsetidinium dication.

Saved in:
Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 47; no. 16; pp. 4817 - 4819
Main Authors Brazeau, Allison L., Nikouline, Anton S., Ragogna, Paul J.
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2011
Subjects
2,2'-Dipyridyl - chemistry
Arsenic
Arsenicals - chemical synthesis
Arsenicals - chemistry
Cations
Cations - chemical synthesis
Cations - chemistry
Chemistry
Chemistry, Multidisciplinary
Crystallography, X-Ray
Ligands
Models, Molecular
Molecular Structure
Physical Sciences
Precursors
Science & Technology
Stereoisomerism
LIGAND
LEWIS-ACID
ANALOGS
COMPLEXES
CATIONS
Online AccessGet full text

Cover

More Information
Summary:A bulky guanidinate ligand has been utilized in supporting a dichloroarsine, which is an excellent precursor to an arsenium cation and a 2,2'-bipyridine base stabilised arsetidinium dication.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
content type line 23
ObjectType-Article-1
ObjectType-Feature-2
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc10949a