A luminescent gold(I)-copper(I) cluster with unprecedented carbon-centered trigonal prismatic hexagold
An unprecedented trigonal prismatic (μ(6)-C)Au(6) structure has been found in a novel gold(I)-copper(I) cluster with a hypercoordinated carbon, [CAu(6)Cu(2)(dppy)(6)](BF(4))(4); the incorporation of copper ions enhances the rigidity and integrity of the cluster and turns on the bright red solution l...
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Published in | Chemical communications (Cambridge, England) Vol. 47; no. 16; pp. 4739 - 4741 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
England
01.01.2011
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Subjects | |
Online Access | Get full text |
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Summary: | An unprecedented trigonal prismatic (μ(6)-C)Au(6) structure has been found in a novel gold(I)-copper(I) cluster with a hypercoordinated carbon, [CAu(6)Cu(2)(dppy)(6)](BF(4))(4); the incorporation of copper ions enhances the rigidity and integrity of the cluster and turns on the bright red solution luminescence. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/c1cc10497g |