A luminescent gold(I)-copper(I) cluster with unprecedented carbon-centered trigonal prismatic hexagold

An unprecedented trigonal prismatic (μ(6)-C)Au(6) structure has been found in a novel gold(I)-copper(I) cluster with a hypercoordinated carbon, [CAu(6)Cu(2)(dppy)(6)](BF(4))(4); the incorporation of copper ions enhances the rigidity and integrity of the cluster and turns on the bright red solution l...

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Published inChemical communications (Cambridge, England) Vol. 47; no. 16; pp. 4739 - 4741
Main Authors Jia, Jian-Hua, Liang, Jing-Xia, Lei, Zhen, Cao, Ze-Xing, Wang, Quan-Ming
Format Journal Article
LanguageEnglish
Published England 01.01.2011
Subjects
Carbon
Carbon - chemistry
Clusters
Copper
Copper - chemistry
Gold - chemistry
Integrity
Luminescence
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Rigidity
Stereoisomerism
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Summary:An unprecedented trigonal prismatic (μ(6)-C)Au(6) structure has been found in a novel gold(I)-copper(I) cluster with a hypercoordinated carbon, [CAu(6)Cu(2)(dppy)(6)](BF(4))(4); the incorporation of copper ions enhances the rigidity and integrity of the cluster and turns on the bright red solution luminescence.
Bibliography:ObjectType-Article-1
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ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc10497g