Novel C@Ni3P Nanoparticles for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol

A series of Ni 3 P and C@Ni 3 P catalyst were prepared by temperature programmed reduction method and characterized by XRD, TEM, N 2 adsorption–desorption, H 2 -chemisorption, FT-IR, XPS and thermogravimetric analysis. Their catalytic performance in the hydrogenation of furfurnal was investigated. T...

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Bibliographic Details
Published inCatalysis letters Vol. 152; no. 3; pp. 883 - 894
Main Authors Tian, Ye, Wang, Yazhou, Zhang, Huiyu, Xiao, Linfei, Wu, Wei
Format Journal Article
LanguageEnglish
Published New York Springer US 01.03.2022
Springer Nature B.V
Subjects
Catalysis
Catalysts
Chemisorption
Chemistry
Chemistry and Materials Science
Furfural
Furfuryl alcohol
Hydrogenation
Industrial Chemistry/Chemical Engineering
Infrared analysis
Nanoparticles
Organometallic Chemistry
Physical Chemistry
Selectivity
Substrates
Thermogravimetric analysis
X ray photoelectron spectroscopy
Furfural
Furfuryl alcohol
Hydrogenation
Nickel phosphide
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Summary:A series of Ni 3 P and C@Ni 3 P catalyst were prepared by temperature programmed reduction method and characterized by XRD, TEM, N 2 adsorption–desorption, H 2 -chemisorption, FT-IR, XPS and thermogravimetric analysis. Their catalytic performance in the hydrogenation of furfurnal was investigated. The 97% furfural conversion and 96.3% furfuryl alcohol selectivity were obtained over C@Ni 3 P-1 catalyst at 160 °C and 1.4 MPa H 2 for 4 h. Furthermore, C@Ni 3 P-1 catalyst showed a high stability in reusing experiments and the satisfactory hydrogenation performance for other substrates. Graphic Abstract
ISSN:1011-372X
1572-879X
DOI:10.1007/s10562-021-03680-y