Study on the Inhibitory Effect of Cystine, Cysteine, and Clutamate as Inhibitors on X100 Pipeline Steel in 1 M HCl

• Published in: Electrocatalysis Vol. 14; no. 5; pp. 720 - 731
• Main Authors: Zhang, Pandong, He, Liang, Sun, Xiaolu, Liu, Xinran, Li, Ping
• Format: Journal Article
• Language: English
• Published: New York Springer US 01.09.2023; Springer Nature B.V
• Subjects: Amino acids; Catalysis; Chemistry; Chemistry and Materials Science; Contact angle; Corrosion; Corrosion effects; Corrosion inhibitors; Cysteine; Cystine; Density functional theory; Economic impact; Electrochemistry; Energy Systems; High strength low alloy steels; Low carbon steels; Physical Chemistry; Structural steels; Weightlessness; Characterization methods; Amino acids; Corrosion inhibitors; X100 pipeline steel; DFT method
• ISSN: 1868-2529; 1868-5994
• DOI: 10.1007/s12678-023-00830-1

Metal corrosion can cause massive economic losses and many safety hazards; thus, metal corrosion inhibition has been a major research direction worldwide. Among the many methods to stop metal corrosion, the addition of corrosion inhibitors is a common method. The use of amino acids as metal corrosion inhibitors not only has the advantage of being economical and efficient but also meets the long-term concept of being environmentally friendly. In this study, the effect on the corrosion behavior of a mild steel (X100 pipeline steel) in 1 M HCl containing the same concentration of the amino groups of cystine (Cys-Cys), cysteine (Cys), and glutamate (Glu) was investigated via density functional theory (DFT) and various characterization methods. These methods include the weightlessness method, electrochemical tests, scanning electron microscopy (SEM), and the contact angle test. The results show that the inhibition efficiency increased with increasing inhibitor concentration; Cys-Cys showed the best inhibition and Glu showed the poorest inhibition for X100 pipeline steel at the same amino group concentration. Furthermore, the results obtained from various characterization methods were generally consistent.