Nb2CTx MXene boosting PEO polymer electrolyte for all-solid-state Li-S batteries: two birds with one stone strategy to enhance Li+ conductivity and polysulfide adsorptivity

• Published in: Rare metals Vol. 42; no. 8; pp. 2562 - 2576
• Main Authors: Liu, Si-Ming, Chen, Meng-Xun, Xie, Ying, Liu, Deng-Hua, Zheng, Jin-Fei, Xiong, Xiang, Jiang, Heng, Wang, Li-Chang, Luo, Heng, Han, Kai
• Format: Journal Article
• Language: English
• Published: Beijing Nonferrous Metals Society of China 01.08.2023; Springer Nature B.V
• Subjects: Adsorptivity; Biomaterials; Chemistry and Materials Science; Electrolytes; Energy; Ethylene oxide; Ion currents; Lithium sulfur batteries; Materials Engineering; Materials Science; Metallic Materials; Molten salt electrolytes; MXenes; Nanoscale Science and Technology; Original Article; Percolation; Photoelectrons; Physical Chemistry; Polyethylene oxide; Polymers; Polysulfides; Product safety; Solid electrolytes; Solid state; X ray photoelectron spectroscopy; CT; Shuttle effect inhibition; All-solid-state Li-S batteries; Nb; Polyethylene oxide (PEO)-based electrolyte; MXene
• ISSN: 1001-0521; 1867-7185
• DOI: 10.1007/s12598-022-02260-2

All-solid-state lithium-sulfur (Li-S) battery is regarded as next-generation high energy density and safety battery system. The key challenge is to develop a compatible high-performance solid-state electrolyte. Herein, a two birds with one stone strategy is proposed to simultaneously enhance Li + conductivity and polysulfide adsorptivity of poly(ethylene oxide) (PEO)-based polymer electrolyte via the integration of Nb 2 CT x MXene. Moreover, the sheet size of Nb 2 CT x MXene is crucial for the enhancement of Li + conductivity and polysulfide adsorptivity, attributing to the difference in a specific surface area related to the percolation effect. By tuning the sheet size of Nb 2 CT x MXene from 500–300 nm to below 100 nm, the ionic conductivity of the PEO electrolyte is increased to 2.62 × 10 −4 S·cm −1 with improved Li + transference number of 0.37 at 60 °C. Furthermore, theoretical calculation and X-ray photoelectron spectroscopy (XPS) conjointly prove that polysulfides could be effectively adsorbed by Nb 2 CT x nanosheets via forming Nb−S bonding to inhibit their shuttle in the PEO framework. As a result, the all-solid-state Li-S cell exhibits an initial capacity of 1149 mAh·g −1 at 0.5C and good cycling stability with 491 mAh·g −1 after 200 cycles. The results demonstrate the necessity of polysulfide inhibition and the application of Nb 2 CT x MXene in PEO-based electrolytes for all-solid-state Li-S batteries. Graphic Abstract