Preparation and performance of multiwall carbon nanotubes/FeNi3/polyaniline composite electrode material for supercapacitors

• Published in: Ionics Vol. 26; no. 5; pp. 2525 - 2536
• Main Authors: Huang, Jing, Song, Xufeng, He, Chunying, Zhang, Zhixin, Qu, Lingxi, Zhao, Dongyu
• Format: Journal Article
• Language: English
• Published: Berlin/Heidelberg Springer Berlin Heidelberg 01.05.2020; Springer Nature B.V
• Subjects: Capacitance; Chemistry; Chemistry and Materials Science; Condensed Matter Physics; Electrochemical analysis; Electrochemistry; Electrode materials; Electrodes; Energy Storage; Materials selection; Morphology; Multi wall carbon nanotubes; Nanocomposites; Optical and Electronic Materials; Original Paper; Polyanilines; Renewable and Green Energy; Supercapacitors; Supercapacitor; Multiwall carbon nanotubes; Composite; Polyaniline
• ISSN: 0947-7047; 1862-0760
• DOI: 10.1007/s11581-019-03357-y

At present, developing a simple, inexpensive, and scalable technology to fabricate an energy storage system remains a challenge. In this study, MWCNTs/FeNi 3 /PANI nanocomposites were prepared by means of in situ polymerization. The morphologies and structure were characterized by the application of various spectral and analytical techniques. When the newly fabricated MWCNTs/FeNi 3 /PANI-20 ternary composite was taken as supercapacitor electrode, the specific capacitance was 398.1 F g −1 at a current density of 0.5 A g −1 . In addition, the assembled symmetric supercapacitors displayed not only an excellent cycling property (80.9% capacitance retention after 2000 charge/discharge cycles) but also a remarkable energy and power density (9.1 Wh kg −1 and 500 W kg −1 ). As revealed by the results, the electrochemical properties of MWCNTs/FeNi 3 /PANI composites can be improved by the synergistic action of various components through the rational selection of electrode materials.