Stitching together SNx units in the coordination sphere of zirconium: assembly of a tris(imido)sulfite and a hydrazidobis(imido)sulfite

Reaction of a zirconium imido and a hydrazinediido complex with bis(trimethylsilyl)sulfur diimide yielded the corresponding formal [2 + 2] cycloaddition products, the trisimidosulfito complex and the hydrazidobis(imido)sulfito complex containing an unprecedented SN2(N-N) unit.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 48; no. 18; pp. 2397 - 2399
Main Authors Gehrmann, Thorsten, Kruck, Matthias, Wadepohl, Hubert, Gade, Lutz H.
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2012
Subjects
Assembly
Chemistry
Chemistry, Multidisciplinary
Cycloaddition
Diimide
Physical Sciences
Science & Technology
Stitching
Zirconium
CYCLOADDITION
DIANION
C-N
COUPLING REACTIONS
CATALYTIC HYDROAMINATION
IMIDO ANALOGS
TITANIUM
METAL-COMPLEXES
POLYSULFUR NITRIDE
AMIDATE COMPLEXES
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Summary:Reaction of a zirconium imido and a hydrazinediido complex with bis(trimethylsilyl)sulfur diimide yielded the corresponding formal [2 + 2] cycloaddition products, the trisimidosulfito complex and the hydrazidobis(imido)sulfito complex containing an unprecedented SN2(N-N) unit.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc17594k