The effect of stress-annealing on the mechanical and magnetic properties of several Fe-based metal-amorphous nano-composite soft magnetic alloys

• Published in: Journal of non-crystalline solids Vol. 600; p. 122037
• Main Authors: Bruno, N.M., Adoo, N.A., Meakins, E., Keylin, V., Feichter, G.E., Noebe, R.D.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.01.2023
• ISSN: 0022-3093
• DOI: 10.1016/j.jnoncrysol.2022.122037

•Magnetic and mechanical properties in four Fe-based MANCs were investigated.•Fracture surfaces demonstrate the influence of internal stress-state on toughness.•Stress-annealing at optimal condition led to 1.14 W·kg−1 core loss (0.1T, 10 kHz). Fe-based metal-amorphous nanocomposites (MANCs) are the subject of many contemporary studies for their unique tunable soft-magnetic properties. The alloys can exhibit some of the smallest losses and highest power storage capabilities of available materials used in electromagnetic inductors. Here, the magnetic and mechanical properties of Fe72.5Nb2Mo2Cu1Si15.5B7 at.%, Fe68.5Co5Ta3Cu1Si16.5B6 at.%, Fe68.5Co5Ta3Cu1Si16B6.5 at.%, and Fe73.5Ta3Cu1Si16B6.5 at.% melt-spun alloys were investigated in relation to their ability to be stress-annealed to tune permeability while simultaneously minimizing losses in tape-wound inductor cores. Mechanical and physical properties of the as-cast and processed ribbons including relaxation and crystallization temperatures and failure strains were measured using thermomechanical analysis (TMA), uniaxial tension, and bend tests to help inform the stress-annealing parameters. Magnetic properties were measured for the as-cast and stress-annealed materials in both wound-cores and flat ribbon strips. The alloys exhibited severe embrittlement during heating, thus creating significant challenges when tuning magnetic properties with an in-line stress-annealing (SA) process. However, when conditions were optimized, core losses as low as 1.14 W·kg−1 were obtained when cores were excited at 10 kHz to a maximum induction field of 0.1 T, which are among the lowest reported in the literature. Based on this preliminary effort, understanding of the stress state in amorphous precursor ribbons prior to SA could reveal the key to developing more robust in-line SA processes for brittle Fe-based MANCs.