Novel palladacycle N-heterocyclic carbene complexes with bidentate [C,N] and terdentate [C,N,N] and [C,N,O] Schiff bases. Synthesis, characterization and crystal structure analysis

• Published in: Journal of organometallic chemistry Vol. 772-773; pp. 192 - 201
• Main Authors: Naya, Leticia, Vázquez-García, Digna, Fernández, Alberto, López-Torres, Margarita, Marcos, Ismael, Lenis, Oscar A., Pereira, M. Teresa, Vila, José M., Fernández, Jesús J.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.12.2014
• Subjects: Imidazolium salts; N-Heterocyclic carbenes; Palladacycles; Schiff base; Schiff base; Imidazolium salts; Palladacycles; N-Heterocyclic carbenes
• ISSN: 0022-328X; 1872-8561
• DOI: 10.1016/j.jorganchem.2014.07.018

Schiff base palladacycles readily reacted with N-heterocyclic carbenes (NHCs) after deprotonation of the corresponding imidazolium salts with K[N(SiMe3)2] to give mononuclear cyclometallated complexes in which the NHC was coordinated trans to the imine nitrogen. The reaction of dinuclear acetate-, 1, or chloro-bridged, 2, 3, complexes gave new mononuclear species, 4–9, after the bridge-splitting reaction, inclusive of acetato/chloride exchange during the purification process. Treatment of the terdentate [C,N,N] metallacycles, 10, 11, with the NHCs gave 12–15 with substitution of the chloro or acetato ligands; the Pd–NMe2 bond remains uncleaved. Reaction of the carbene ligands with the tetranuclear palladacycle, 16, gave 17–20, after splitting of the parent structure, but without ring opening of neither the Pd–N nor of the Pd–O bonds, hence retaining the metallated and coordination rings at the metal. The structures of 6, 7 and 19 have been determined by single crystal X-ray diffraction. The synthesis and several solid-state structures of new palladacycles with bidentate [C,N], and terdentate [C,N,N] and [C,N,O] Schiff bases and carbene ligands are reported. The NHCs react with the tetranuclear [C,N,O] complexes to give palladacycle units with retention of the palladium–nitrogen and palladium–oxygen bonds. [Display omitted] •Reactivity of palladaycles bearing bidentate [C,N] and terdentate [C,N,X] (X = O, N) ligands towards carbenes.•Equilibrium in Schiff base palladacycles with carbene ligands.•X-ray crystallographic studies of a cyclopalladated complexes with carbenes.