Investigation of luminescence parameters of novel glasses with composition TeO2-ZnO-NaF-MoO2-Er2O3 as laser material

• Published in: Journal of non-crystalline solids Vol. 498; pp. 72 - 81
• Main Authors: AbouDeif, Y.M., Yousef, El Sayed, Marzouk, Samir Y.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.10.2018
• Subjects: Density; Emission cross section; Gain cross-section; Judd-Ofelt analysis; Optical energy gap; Oxide glasses; Refractive index; UV–vis-NIR; UV–vis-NIR; Emission cross section; Refractive index; Judd-Ofelt analysis; Oxide glasses; Optical energy gap; Density; Gain cross-section
• ISSN: 0022-3093; 1873-4812
• DOI: 10.1016/j.jnoncrysol.2018.05.024

Fluoroquaternary glasses within system 70TeO2-10ZnO-10NaF-(10 − x)MoO2-xEr2O3 doped with different concentration of xEr2O3 ions were prepared by using melt- quenching technique. The amorphous nature of the glasses confirmed by using X-ray diffraction. Physical parameters viz.: density (ρ), molar volumes (Vm), refractive index (n), an optical energy gap (Eg) and Urbach energy (ΔE) values of prepared glasses were evaluated. Moreover, the Judd–Ofelt parameters Ω2, Ω4, Ω6, the oscillator strength type transition probabilities, Smeas, Scal, spectroscopic quality factors, X, branching ratio, βR and radiative lifetimes, τR, of several excited states of Er3+ have been computed. The gain cross-section of laser transition level from 4I13/2 → 4I15/2 and stimulated emission cross-section estimated with different concentration of Er2O3 ions in all present glasses. Here the spectroscopic properties indicate that these glasses doped with Er3+ are a promising candidate for optical applications. •The incorporation of Er2O3 into the ternary fluoroglasses leads to increase linear refractive index (n) and Urbach energy (ΔE).•JO spectroscopic parameters changed in the trend Ω2 > Ω4 > Ω6 for all glasses were prepared.•The stimulated emission cross-section σe and the optical gain cross section σgain decreases with increasing Er3+ doped glasses (TeEr0.5 to TeEr5).