Symmetrical polyhedron-bowl Co/CoO with hexagonal plate to forward electromagnetic wave absorption ability

• Published in: CrystEngComm Vol. 21; no. 5; pp. 816 - 826
• Main Authors: Zhao, Biao, Li, Yang, Liu, Junwei, Fan, Lei, Gao, Ka, Bai, Zhongyi, Liang, Luyang, Guo, Xiaoqin, Zhang, Rui
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 2019
• Subjects: Composite materials; Current loss; Electromagnetic radiation; Leakage current; Microwave absorption; Morphology; Paraffins; Plates (structural members); Polyhedra; Reflection; Thickness
• ISSN: 1466-8033; 1466-8033
• DOI: 10.1039/c8ce01677a

Symmetrical polyhedron-bowl (twin-hexagonal frustum-pyramid) structured Co/CoO products were prepared via a simple polyol reduction approach. The effects of reaction conditions (solvent constituents and reaction times) on the morphologies of Co/CoO products were investigated in detail. The microwave absorption performances of Co/CoO polyhedron paraffin composites with various Co/CoO contents were also studied. The results showed that the Co/CoO polyhedron paraffin composites exhibit enhanced microwave absorption properties with an increased Co/CoO content in the certain amount range. This phenomenon is observed because the conductive networks are gradually formed to cause leakage current loss with increasing Co/CoO content. However, the large leakage current induces impedance mismatch to prohibit microwaves from entering absorbers with a relatively high Co/CoO content. Thus, the Co/CoO polyhedrons paraffin composite with 50 wt% Co/CoO displays excellent microwave absorption properties. The optimal reflection loss (RL) is −45.3 dB at 12.5 GHz with a thickness of 1.7 mm. The effective absorption (below −10 dB) bandwidth can be tuned to the frequency of 4.5-18.0 GHz with thickness of 1.0-4.0 mm. The abundant reflection and scattering were caused by the symmetrical polyhedron-bowl structure. The micro-capacitors formed between Co/CoO as electrodes, paraffin as a dielectric, and the interfacial polarization collectively contribute to microwave absorption abilities. The symmetrical polyhedron-bowl structured Co/CoO displays enhanced microwave absorption properties.