Effects of argon/nitrogen sputtering gas on the microstructural, crystallographic and piezoelectric properties of AlN thin films

• Published in: Scripta materialia Vol. 226; p. 115228
• Main Authors: Samad, Muhammad Izzuddin Abd, Noor, Mimiwaty Mohd, Nayan, Nafarizal, Bakar, Ahmad Shuhaimi Abu, Mansor, Marwan, Zuhdi, Ahmad Wafi Mahmood, Hamzah, Azrul Azlan, Latif, Rhonira
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 15.03.2023
• Subjects: Aluminium nitride; Argon plasma; Crystallography; Piezoelectric force microscopy (PFM); Radio frequency (RF) sputtering; Piezoelectric force microscopy (PFM); Radio frequency (RF) sputtering; Crystallography; Aluminium nitride; Argon plasma
• ISSN: 1359-6462; 1872-8456
• DOI: 10.1016/j.scriptamat.2022.115228

•Deposit AlN ‹002› thin film on Mo/Si substrate using AlN ceramic target without substrate heating.•The purity of nitrogen gas dominates the physical quality and chemical properties of AlN thin film.•AlN ‹002› thin film exhibits different piezoelectric characteristics compared to AlN ‹100›. The growth of highly crystalline c-plane AlN ‹002› is extremely difficult, entailing high temperature and ultra-high vacuum condition. In sputtering technique, the addition of nitrogen into argon sputtering gas can significantly assist the formation of AlN ‹002› at low temperature. We incorporated purified nitrogen gas and observed the consistent formation of single crystal ‹002› AlN thin film layer sputter-deposited on Mo/Si substrate from the AlN ceramic target. Small presence of oxygen content within AlN crystal relates to the preferential growth of AlN ‹002›. High oxygen content in AlN thin film due to the use of unpurified nitrogen and argon only sputtering gas prefers the formation of AlN ‹100›. Different AlN crystal structure has shown distinct thin film properties and piezoelectric response. This work provides a method to control the crystal structure of the sputter-deposited AlN thin film layer, either c-plane AlN ‹002›, a-plane AlN ‹100› or polycrystalline AlN. [Display omitted]