An unusual reaction of cyclopropenylphosphonium bromide with sodium polyphosphides – A novel approach to sodium 3,4,5-triphenyl-1,2-diphosphacyclopentadienide

1,2,3-Triphenylcyclopropenylphosphonium bromide reacts with sodium polyphosphides to give sodium 3,4,5-triphenyl-1,2-diphosphacyclopentadienide in high yield. 1,2,3-Triphenylcyclopropenylphosphonium bromide reacts with sodium polyphosphides to give sodium 3,4,5-triphenyl-1,2-diphosphacyclopentadieni...

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Published inJournal of organometallic chemistry Vol. 693; no. 21; pp. 3318 - 3320
Main Authors Bezkishko, Ilya, Miluykov, Vasily, Kataev, Alexander, Litvinov, Igor, Krivolapov, Dmitry, Sinyashin, Oleg, Hey-Hawkins, Evamarie
Format Journal Article
LanguageEnglish
Published LAUSANNE Elsevier B.V 15.10.2008
Elsevier
Subjects
1,2-Diphosphacyclopentadienide anion
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Phosphonium salt
Physical Sciences
Science & Technology
Sodium polyphosphides
Triphenylcyclopropenyl bromide
1,2-Diphosphacyclopentadienide anion
Triphenylcyclopropenyl bromide
Phosphonium salt
Sodium polyphosphides
phosphonium salt
MOLECULAR-STRUCTURE
COMPLEXES
triphenylcyclopropenyl bromide
1,2-diphosphacyclopentadienide anion
sodium polyphosphides
CRYSTAL
CATIONS
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Summary:1,2,3-Triphenylcyclopropenylphosphonium bromide reacts with sodium polyphosphides to give sodium 3,4,5-triphenyl-1,2-diphosphacyclopentadienide in high yield. 1,2,3-Triphenylcyclopropenylphosphonium bromide reacts with sodium polyphosphides to give sodium 3,4,5-triphenyl-1,2-diphosphacyclopentadienide in high yield.
ISSN:0022-328X
1872-8561
DOI:10.1016/j.jorganchem.2008.08.006