Simultaneous increase in piezoelectric response and Curie point in BaTiO3 based Pb-free piezoceramic

Piezoelectric ceramics are used in wide-ranging applications as actuators, transducers, and sensors. For applications at ambient environmental conditions, it is desirable that the piezoelectric material exhibit large piezoelectric coefficient (d33) and possess Curie point well above room temperature...

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Bibliographic Details
Published inScripta materialia Vol. 243; p. 115994
Main Authors Tina, Getaw Abebe, Punetha, Pooja, Adhikary, Gobinda Das, Ranjan, Rajeev
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.04.2024
Subjects
BaTiO3
Ferroelectrics
Lead-free piezoelectrics
Perovskites
Piezoceramics
Perovskites
Lead-free piezoelectrics
Ferroelectrics
BaTiO3
Piezoceramics
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Summary:Piezoelectric ceramics are used in wide-ranging applications as actuators, transducers, and sensors. For applications at ambient environmental conditions, it is desirable that the piezoelectric material exhibit large piezoelectric coefficient (d33) and possess Curie point well above room temperature. Among the lead-free piezoelectrics, the classical ferroelectric BaTiO3 exhibits Curie point and d33 ∼ 120 °C and 190 pC/N, respectively. Most attempts at improving the d33 of BaTiO3 via chemical modifications significantly reduces the Curie point (Tc). Here we show that it is possible to improve both the d33 and Tc of BaTiO3. We found this possibility while investigating a solid solution of BaTiO3 with BaAlO2.5. An optimum composition, 0.97 BaTiO3-0.03BaAlO2.5 of this solid solution exhibit d33 ∼356 pC/N, Curie point 125 °C, and good thermal stability of the piezo response. [Display omitted]
ISSN:1359-6462
1872-8456
DOI:10.1016/j.scriptamat.2024.115994