Synthesis and characterization of new (dimethylsilyl)phenoxy and (dimethyl(vinyl)silyl)phenoxy substituted cyclotriphosphazenes

The routes of synthesis, as well as, spectroscopic and X-ray diffraction characterization of a new group of bis- or hexakis-4-(dimethyl(vinyl)silyl)phenoxy and 4-(dimethylsilyl)phenoxy-substituted cyclotriphosphazenes as a versatile starting substrates for the synthesis of a variety of organic cyclo...

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Published inJournal of organometallic chemistry Vol. 853; pp. 64 - 67
Main Authors Januszewski, Rafał, Dutkiewicz, Michał, Kubicki, Maciej, Dutkiewicz, Grzegorz, Maciejewski, Hieronim, Marciniec, Bogdan
Format Journal Article
LanguageEnglish
Published LAUSANNE Elsevier B.V 15.12.2017
Elsevier
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Cyclophosphazene
Dimethylsilylphenoxy
Nucleophilic substitution
Physical Sciences
Science & Technology
Dimethylsilylphenoxy
Cyclophosphazene
ZLTHRNKUZHDXCG-UHFFFAOYSA-N
ZIWLYIBNGRLSQH-UHFFFAOYSA-N
LZDZRKDTUHPPOI-UHFFFAOYSA-N
GHFUKCKGUWSJPV-UHFFFAOYSA-N
NQTSPLLFKAZMKQ-UHFFFAOYSA-N
APEOBACEKHZYKC-UHFFFAOYSA-N
Nucleophilic substitution
RPJANBOAICDMQD-UHFFFAOYSA-N
UBIJTWDKTYCPMQ-UHFFFAOYSA-N
POLYMERS
PHOSPHAZENE
DIOXYBIPHENYL
SILICON
POLYMERIZATION
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Summary:The routes of synthesis, as well as, spectroscopic and X-ray diffraction characterization of a new group of bis- or hexakis-4-(dimethyl(vinyl)silyl)phenoxy and 4-(dimethylsilyl)phenoxy-substituted cyclotriphosphazenes as a versatile starting substrates for the synthesis of a variety of organic cyclophosphazene derivatives, via catalytic hydrosilylation or silylative coupling processes, is presented. [Display omitted] •Path of synthesis of dimethylsilylphenoxy substituted cyclophosphazenes is presented.•Spectral and x-ray characteristic of new derivatives is given.•Obtained compounds are useful substrates for their further catalytic transformations.•These compounds can be alternatives for conventional silicone rubber cross-linkers.
ISSN:0022-328X
1872-8561
DOI:10.1016/j.jorganchem.2017.10.030