New paramagnetic N-heterocyclic stannylenes: An EPR study

The reactions of N,N′-bis[(2,6-di- iso-propylphenyl)-1,2,3-diazastannole-2-ylidene with some radicals, mercury(II) or silver(I) halides have been investigated. The formation of new paramagnetic stannylene complexes has been shown by EPR spectroscopy. The reactions of N,N′-bis[(2,6-di- iso-propylphen...

Full description

Saved in:
Bibliographic Details
Published inJournal of organometallic chemistry Vol. 691; no. 8; pp. 1531 - 1534
Main Authors Piskunov, Alexander V., Aivaz’yan, Igor A., Cherkasov, Vladimir K., Abakumov, Gleb A.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.04.2006
Subjects
EPR
Oxidation
Paramagnetic complex
Radical addition
Stannylene
Oxidation
Stannylene
Paramagnetic complex
EPR
Radical addition
Online AccessGet full text

Cover

More Information
Summary:The reactions of N,N′-bis[(2,6-di- iso-propylphenyl)-1,2,3-diazastannole-2-ylidene with some radicals, mercury(II) or silver(I) halides have been investigated. The formation of new paramagnetic stannylene complexes has been shown by EPR spectroscopy. The reactions of N,N′-bis[(2,6-di- iso-propylphenyl)-1,2,3-diazastannole-2-ylidene with some radicals, mercury(II) or silver(I) halides have been investigated. The formation of new paramagnetic stannylene complexes has been shown by EPR spectroscopy.
ISSN:0022-328X
1872-8561
DOI:10.1016/j.jorganchem.2005.11.064