Reduction of electromagnetic signature by the epoxy-based nanocomposite with ferrite@ferrite nanostructure

• Published in: Composites science and technology Vol. 267; p. 111202
• Main Authors: Radoń, Adrian, Kopyciński, Bartosz, Ciuraszkiewicz, Agnieszka, Kubacki, Jerzy, Kądziołka-Gaweł, Mariola, Łukowiec, Dariusz, Gębara, Piotr, Langer, Ewa, Kolano-Burian, Aleksandra
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 07.07.2025
• Subjects: Core-shell; EMI shielding; Ferrites; Microwave absorption; Nanoparticles; Ferrites; Nanoparticles; Microwave absorption; Core-shell; EMI shielding
• ISSN: 0266-3538
• DOI: 10.1016/j.compscitech.2025.111202

The highly efficient electromagnetic interference (EMI) shielding materials that can be applied for signature reduction are the subject of numerous studies due to their applicability potential in the military and aerospace fields. A novel approach to characterize epoxy-based nanocomposites with complex ferrite nanostructures was used and applied in order to determine the possibility of using an epoxy-based nanocomposite with ferrite@ferrite nanostructure as a signature reduction material. Two nanostructures, i.e. Fe3O4@CoFe2O4 and Fe3O4@NiZnFe2O4, were developed, and their magnetic and dielectric properties were compared with the pure core – Fe3O4. Analysis of magnetodielectric properties allowed us to choose the bi-magnetic Fe3O4@CoFe2O4 nanostructure as the most adequate one for preparing the nanocomposite with high EMI shielding performance. An epoxy-based nanocomposite with these nanoparticles and an organic filler (amorphous yellow dextrin and rice starch mixture) was prepared. The shielding efficiency analysis in the transmission and reflection modes confirmed that the composite with 50 wt% of Fe3O4@CoFe2O4 can enhance the absorption of electromagnetic radiation. A reduction of the reflectivity from 0.97 to 0.45 and the increase in absorptivity from 0.03 to 0.55 at 8 GHz compared to pure polymer matrix backed by a metallic plate, was observed. Also, shielding efficiency related to the reflection of the electromagnetic wave decreased from 14.74 dB to 2.61 dB, confirming a change of the EMI shielding mechanism from reflection (for metallic components) to absorption (for metallic surface covered by a nanocomposite). [Display omitted] •The formation of 2nd ferrite on the Fe3O4 core is related to the consumption of this phase.•Reflectivity, absorptivity, and transmittivity were used to analyze the EMI shielding mechanism.•Shielding efficiency based on reflection (SER) must be minimized to ensure high microwave absorption.•The Fe3O4@CoFe2O4 – based composite can reduce the reflectivity of metallic surfaces.•The addition of 50 wt% of Fe3O4@CoFe2O4 results in a decrease of SER even 5 times.