Functionalized Thermo-Responsive Poly(vinyl ether) by Living Cationic Random Copolymerization of Methyl Vinyl Ether and 2-Chloroethyl Vinyl Ether
The living cationic random copolymerization of MVE and CEVE to obtain functionalized thermo‐responsive PMVE as precursors for more complex PMVE‐containing polymer structures is reported. The random copolymers P(MVE‐co‐CEVE) were synthesized at 0 °C in toluene using the DEE/TMSI/ZnI2 initiating syste...
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Published in | Macromolecular chemistry and physics Vol. 208; no. 17; pp. 1871 - 1882 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
Weinheim
WILEY-VCH Verlag
05.09.2007
WILEY‐VCH Verlag Wiley |
Subjects | |
Online Access | Get full text |
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Summary: | The living cationic random copolymerization of MVE and CEVE to obtain functionalized thermo‐responsive PMVE as precursors for more complex PMVE‐containing polymer structures is reported. The random copolymers P(MVE‐co‐CEVE) were synthesized at 0 °C in toluene using the DEE/TMSI/ZnI2 initiating system. The monomer reactivity ratios of these copolymers are determined according to the extended Kelen‐Tüdõs procedure: rCEVE = 0.48 ± 0.04 and rMVE = 0.76 ± 0.05. The cloud point temperatures of the random copolymers are found to depend strongly on the composition of the copolymer and disappeared at CEVE contents above 3 mol‐%. |
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Bibliography: | Belgian Programme on Interuniversity Attraction Poles initiated by the Belgian State, Prime Minister's office - No. P6/27 ArticleID:MACP200700205 istex:BAB0FB3B3E590D69BCCF3EB873BEAA40FB9D462E ark:/67375/WNG-H71XC7N9-R ESF-programme STIPOMAT ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
ISSN: | 1022-1352 1521-3935 |
DOI: | 10.1002/macp.200700205 |