Dirhodium(II)-Catalyzed Synthesis of N-(Arylsulfonyl)hydrazines by N–H Amination of Aliphatic Amines

Abstract This study reports the development of Rh(II)-catalyzed N–N bond-forming reaction of amino acid derivatives or aliphatic amines to provide hydrazine derivatives through the combined use of Rh 2 (esp) 2 and [(3,4-dimethoxyphenyl)sulfonylimino]-2,4,6-trimethylphenyliodinane (3,4-(MeO) 2 C 6 H...

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Published inSynlett Vol. 33; no. 4; pp. 367 - 370
Main Authors Ito, Motoki, Hasegawa, Yui, Saito, Satomi, Onda, Asami, Higuchi, Kazuhiro, Sugiyama, Shigeo
Format Journal Article
LanguageEnglish
Published Rüdigerstraße 14, 70469 Stuttgart, Germany Georg Thieme Verlag KG 02.03.2022
Subjects
letter
nitrene
hydrazine
Rh(II) catalyst
amine
N–N bond
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Summary:Abstract This study reports the development of Rh(II)-catalyzed N–N bond-forming reaction of amino acid derivatives or aliphatic amines to provide hydrazine derivatives through the combined use of Rh 2 (esp) 2 and [(3,4-dimethoxyphenyl)sulfonylimino]-2,4,6-trimethylphenyliodinane (3,4-(MeO) 2 C 6 H 3 SO 2 N=IMes). This is the first report of N–H amination of aliphatic amines with metal–nitrene species.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-0041-1737759