Oxalic acid hydrogenation to glycolic acid: heterogeneous catalysts screening

• Published in: Green chemistry : an international journal and green chemistry resource : GC Vol. 25; no. 6; pp. 249 - 2426
• Main Authors: Schuler, Eric, Grooten, Lars, Kasireddy, Mohanreddy, More, Santosh, Shiju, N. Raveendran, Tanielyan, Setrak K, Augustine, Robert L, Gruter, Gert-Jan M
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 20.03.2023
• Subjects: Acetic acid; Acids; Carbon dioxide; Carbon dioxide emissions; Catalysts; Chemical reduction; Design parameters; Direct conversion; Direct reduction; Electrochemistry; Emissions; Esterification; Esters; Ethylene; Ethylene glycol; Formic acid; Glycolic acid; Green chemistry; Intermediates; Monomers; Oxalic acid; Ruthenium; Selectivity; Tin
• ISSN: 1463-9262; 1463-9270
• DOI: 10.1039/d2gc02411j

To meet our ambitions of a future circular economy and drastically reduce CO 2 emissions, we need to make use of CO 2 as a feedstock. Turning CO 2 into monomers to produce sustainable plastics is an attractive option for this purpose. It can be achieved by electrochemical reduction of CO 2 to formic acid derivatives, that can subsequently be converted into oxalic acid. Oxalic acid can be a monomer itself and it is a potential new platform chemical for material production, as useful monomers such as glycolic acid and ethylene glycol can be derived from it. Today the most common route from oxalic acid to glycolic acid requires multiple steps as it proceeds via oxalic acid di-esters as intermediates. In this work, we aim to avoid the extra reaction step of esterification. We explore the direct conversion of oxalic acid to glycolic acid in a two-step approach. In the first step, we define the ideal reaction conditions and test commercially available catalysts. We show that the reduction of oxalic acid can be performed at much lower temperatures and glycolic acid yields higher than those reported previously can be obtained. In the second step, we explore the design principles required for ideal catalysts which avoid the formation of acetic acid and ethylene glycol as side products. We show that ruthenium is the most active metal for the reaction and that carbon appears the most suitable support for these catalysts. By adding tin as a promotor, we could increase the selectivity and yield further whilst maintaining high activity of the resulting catalyst. This research lays the foundation for the efficient direct reduction of oxalic acid to glycolic acid and defines the design parameters for even better catalysts and the ideal process and conditions. This article explores a CO 2 utilization option by investigating sustainable and economic catalytic conversion of CO 2 -based oxalic acid to glycolic acid monomer. Ideal catalyst design principles and reaction conditions were established for this novel conversion process.