The same oxygenation-state introduction of hypervalent sulfur under transition-metal-free conditions

Sulfonyl compounds have attracted considerable interest due to their extensive applications in drug discovery. Access to the assembly of SO2-containing compounds via the oxygenation oxidative-state introduction of hypervalent sulfur has come to the fore in recent years. This review discusses the app...

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Published inOrganic chemistry frontiers an international journal of organic chemistry Vol. 7; no. 23; pp. 3956 - 3966
Main Authors Zeng, Daming, Wang, Ming, Wei-Ping, Deng, Jiang, Xuefeng
Format Journal Article
LanguageEnglish
Published London Royal Society of Chemistry 07.12.2020
Subjects
Fluorides
Organic chemistry
Oxygenation
Sulfonamides
Sulfones
Sulfur
Sulfur dioxide
Transition metals
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Summary:Sulfonyl compounds have attracted considerable interest due to their extensive applications in drug discovery. Access to the assembly of SO2-containing compounds via the oxygenation oxidative-state introduction of hypervalent sulfur has come to the fore in recent years. This review discusses the application of the same oxygenation-state introduction of hypervalent sulfur strategy under transition-metal-free conditions, and presents it in light of different atoms being linked to the sulfonyl group, including sulfones, sulfonamides, sulfonyl fluorides and thiosulfonates.
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ISSN:2052-4110
2052-4110
DOI:10.1039/d0qo00987c