Recent Advances in Visible‐Light‐Mediated Synthesis of Phosphorylated Heterocycles

Organophosphorus compounds, especially phosphorylated heterocycles, are gaining increasing attention in the fields of materials science, pharmaceuticals, and agrochemistry due to their excellent biological activities. Consequently, the exploration of green and efficient methods for the synthesis of...

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Bibliographic Details
Published inAdvanced synthesis & catalysis Vol. 366; no. 22; pp. 4536 - 4547
Main Authors Zeng, Fan‐lin, Jia, Zhenhua, Loh, Teck‐Peng
Format Journal Article
LanguageEnglish
Published Heidelberg Wiley Subscription Services, Inc 19.11.2024
Subjects
Chemical reactions
Chemical synthesis
Cross coupling
Heterocycles
Organophosphorus compounds
Phosphine oxide
Phosphorylation
Radical reaction
Visible-Light
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ISSN1615-4150
1615-4169
DOI10.1002/adsc.202400819

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Summary:Organophosphorus compounds, especially phosphorylated heterocycles, are gaining increasing attention in the fields of materials science, pharmaceuticals, and agrochemistry due to their excellent biological activities. Consequently, the exploration of green and efficient methods for the synthesis of phosphorylated heterocycles has garnered significant interest from organic chemists. In recent years, visible light‐induced photoredox‐catalyzed organic synthesis has made substantial progress in the field of phosphorylation reaction since its eco‐friendly and mild conditions. This review summarizes the advances of the past five years in the visible‐light‐mediated synthesis of phosphorylated heterocycles using phosphine oxides as precursors through P‐centered radical addition, cross‐coupling, and cyclization reactions.
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ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.202400819