Optical Resonances of Chiral Metastructures in the Mid‐infrared Spectral Range

• Published in: Israel journal of chemistry Vol. 63; no. 12
• Main Authors: Therien, Denis A. B., Read, Stuart T., Rosendahl, Scott M., Lagugné‐Labarthet, François
• Format: Journal Article
• Language: English
• Published: Haifa Wiley Subscription Services, Inc 01.12.2023
• Subjects: Chiral Plasmons; Chirality; Circular polarization; Dichroism; Electron beam lithography; Finite-Difference Time-Domain (FDTD) Modelling; Infrared spectra; Metamaterials; Mid-Infrared Plasmonics; Optical resonance; Plasmon Resonance Tuning; Sensitivity enhancement; Surface plasmon resonance; Vibrational Circular Dichroism (VCD)
• ISSN: 0021-2148; 1869-5868
• DOI: 10.1002/ijch.202200007

Metamaterials with localized surface plasmon resonances have been the subject of intense research for a wealth of applications ranging from active photonic devices to analytical sensing units that utilizes the local field enhancement to improve sensitivity and decrease acquisition time. Herein, we focus on the modelled properties of a series of spiral metastructures that present multiple chiral plasmon modes in the 1–10 μm mid‐IR spectral range and that could be utilized to enhance vibrational circular dichroism measurements to further identify molecular, supramolecular and structural chirality centres. Finite‐difference time‐domain electromagnetic modelling was conducted to calculate the infrared spectra of the metastructures in response to a circularly polarized excitation. Several geometric parameters were altered to further tune the position of the resonances. In addition, the near‐field distribution of the optical resonances was calculated providing a spatial snapshot of the chiral modes. Preliminary spiral structures were fabricated using electron beam lithography and their vibrational circular response was measured.