Sulfenylation of C–H Bonds for C–S Bond Formation under Metal‐Free Conditions

Sulfenylation of C–H bonds for C–S bond formation under metal‐free conditions has become established as a powerful tool in organic chemistry. Various sulfenylation reagents such as thiols, disulfides, sulfinic acids, and so on have been employed for sulfenynlation reactions. In this review we mainly...

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Published inEuropean journal of organic chemistry Vol. 2017; no. 45; pp. 6576 - 6592
Main Authors Dong, Dao‐Qing, Hao, Shuang‐Hong, Yang, Dao‐Shan, Li, Li‐Xia, Wang, Zu‐Li
Format Journal Article
LanguageEnglish
Published Weinheim Wiley Subscription Services, Inc 08.12.2017
Subjects
Aromatic substitution
Chemical bonds
C–S bonds
Disulfides
Metal‐free
Organic chemistry
Reaction mechanisms
Reagents
Succinimides
Sulfenylation
Synthetic methods
Thiols
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Summary:Sulfenylation of C–H bonds for C–S bond formation under metal‐free conditions has become established as a powerful tool in organic chemistry. Various sulfenylation reagents such as thiols, disulfides, sulfinic acids, and so on have been employed for sulfenynlation reactions. In this review we mainly summarize the recent advances (2014 to the present) in this area and also discuss the mechanisms. Sulfenylation of C–H bonds has recently come to receive more and more attention. In this Microreview, recent advances in sulfenylation of C–H bonds for C–S bond formation under metal‐free conditions are reviewed.
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.201700853