Palladium‐Catalyzed Annulation of Arylbenzamides with Diaryliodonium Salts

By using diaryliodonium salts, a cylization has been accomplished in the synthesis of N‐aryl phenanthridinone derivatives via a cascade of ortho‐arylation and Csp2‐N bond formation in the presence of palladium catalyst. The reaction exhibits a broad compatibility of readily available N‐arylnaphthami...

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Bibliographic Details
Published inAdvanced synthesis & catalysis Vol. 364; no. 2; pp. 268 - 273
Main Authors Pan, Cheng, Wang, Limin, Han, Jianwei
Format Journal Article
LanguageEnglish
Published WEINHEIM Wiley 18.01.2022
Wiley Subscription Services, Inc
Subjects
Cascade reaction
Chemical reactions
Chemistry
Chemistry, Applied
Chemistry, Organic
Diaryliodonium
Palladium
Palladium catalysis
Physical Sciences
Science & Technology
π-Extension
Cascade reaction
ACTIVATION
C-H BOND
DUAL FLUORESCENCE
ARYLATION
Diaryliodonium
OXIDATIVE ANNULATION
PHENANTHRIDINONE
INTRAMOLECULAR CHARGE-TRANSFER
BENZAMIDES
Palladium catalysis
NITRILES
pi-Extension
CASCADE ANNULATION
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ISSN1615-4150
1615-4169
DOI10.1002/adsc.202100860

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Summary:By using diaryliodonium salts, a cylization has been accomplished in the synthesis of N‐aryl phenanthridinone derivatives via a cascade of ortho‐arylation and Csp2‐N bond formation in the presence of palladium catalyst. The reaction exhibits a broad compatibility of readily available N‐arylnaphthamides.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.202100860