Highly Durable and Active Ternary Pt–Au–Ni Electrocatalyst for Oxygen Reduction Reaction

• Published in: ChemCatChem Vol. 10; no. 14; pp. 3049 - 3056
• Main Authors: Liu, Fei, Sun, Kui, Rui, Zhiyan, Liu, Jianguo, Juan, Tian, Liu, Ruirui, Luo, Jun, Wang, Zhongwei, Yao, Yingfang, Huang, Lin, Wang, Peng, Zou, Zhigang
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 19.07.2018
• Subjects: Accelerated tests; Catalysis; Catalysts; Commercialization; electrochemistry; fuel cells; Gold; oxygen; Oxygen reduction reactions; Platinum; Proton exchange membrane fuel cells; reduction; Stability
• ISSN: 1867-3880; 1867-3899
• DOI: 10.1002/cctc.201800360

Long‐term stable and high active catalysts for oxygen reduction reaction (ORR) are required for the commercialization of proton exchange membrane fuel cells (PEMFCs). Platinum (Pt) catalyst is the preferred choose for ORR, but the stability and activity of existing Pt catalyst are unsatisfactory for the commercialization of PEMFCs. Here the ternary Pt–Au–Ni/C and binary Pt–Ni/C are synthesized by a rapid microwave‐assisted polyol reduction. The Pt–Au–Ni/C exhibits superior ORR activity to both of Pt–Ni/C and commercial Pt/C. Moreover, the Pt–Au–Ni/C exhibited the long‐term stability in both of half‐cell and single‐cell accelerated degradation tests. The above results indicate that the addition of Au into binary Pt–Ni catalyst can not only enhance the stability but also improve the electrocatalytic activity. Golden stabilizer: The polarization curves in the oxygen reduction reaction are compared for commercial Pt/C, Pt–Ni/C and Pt–Au–Ni/C electrocatalysts before and after accelerated degradation testing. Addition of Au into binary Pt–Ni catalyst enhances both stability and electrocatalytic activity.