Rietveld refinement and electrical properties of cadmium lithium phosphate

Cadmium lithium phosphate, LiCdPO 4 , has been prepared by the solid state reaction method and characterized by X-ray powder diffraction at room temperature. This compound crystallizes in the orthorhombic system with Pnma space group. Vibrational study by means of Raman spectroscopy confirms the exi...

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Bibliographic Details
Published inJournal of materials science. Materials in electronics Vol. 28; no. 18; pp. 13806 - 13813
Main Authors Djemal, Amal, Louati, Bassem, Guidara, Kamel
Format Journal Article
LanguageEnglish
Published New York Springer US 01.09.2017
Springer Nature B.V
Subjects
Cadmium
Characterization and Evaluation of Materials
Chemistry and Materials Science
Electrical properties
Electrical resistivity
Fractals
Functional groups
Lithium
Materials Science
Optical and Electronic Materials
Spectrum analysis
X ray powder diffraction
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Summary:Cadmium lithium phosphate, LiCdPO 4 , has been prepared by the solid state reaction method and characterized by X-ray powder diffraction at room temperature. This compound crystallizes in the orthorhombic system with Pnma space group. Vibrational study by means of Raman spectroscopy confirms the existence of the (PO 4 ) 3− functional group. The electrical properties have been investigated in the frequency range 209 Hz–1 MHz and temperature range 584–686 K. Experimental measurements of ac conductivity were fitted by the Jonscher’s universal power law: σ a c = σ d c + A ω n .
ISSN:0957-4522
1573-482X
DOI:10.1007/s10854-017-7226-6